\u5e38\u7528\u50ac\u5316\u5242\u7c7b<\/strong><\/a><\/p>\n\u5e38\u7528\u8bd5\u5242—-\u918b\u9178\u94af<\/p>\n
\u5e38\u7528\u50ac\u5316\u5242—-\u4e8c\u6c2f[1,2-\u4e8c(\u4e8c\u57fa\u81a6)\u4e59\u70f7]\u94af<\/p>\n
\u5e38\u7528\u50ac\u5316\u5242—-Pd(dppf)Cl2<\/p>\n
\u5e38\u7528\u50ac\u5316\u5242—-\u56db(\u4e09\u57fa\u81a6)\u94af<\/p>\n
\u5e38\u7528\u50ac\u5316\u5242—-\u4e8c(\u4e09\u57fa\u81a6)\u918b\u9178\u94af<\/p>\n
\u5e38\u7528\u50ac\u5316\u5242—-\u94af-\u94a1<\/p>\n
\u5e38\u7528\u50ac\u5316\u5242—-Lindlar\u50ac\u5316\u5242<\/p>\n
\u5e38\u7528\u50ac\u5316\u5242—-\u4e8c\u6c2f\u4e09(\u4e09\u57fa\u81a6)\u948c<\/p>\n
\u5e38\u7528\u50ac\u5316\u5242—-\u948c\u50ac\u5316\u5242<\/p>\n
\u5e38\u7528\u50ac\u5316\u5242—-\u73af\u620a\u4e8c\u70ef\u57fa\u53cc\u4e09\u57fa\u81a6\u5408\u94b4(I)<\/p>\n
\u5e38\u7528\u50ac\u5316\u5242—-(R,R)-Jacobsen \u50ac\u5316\u5242<\/p>\n
\u5e38\u7528\u50ac\u5316\u5242—-Cu(acac)2<\/p>\n
\u5e38\u7528\u50ac\u5316\u5242—-(DIOP)PdCl2<\/p>\n
\u5e38\u7528\u6c27\u5316\u5242—-OsO4\/NMO<\/p>\n
\u5e38\u7528\u6c27\u5316\u5242—-\u56db\u6c27\u5316\u9507-\u94c1\u6c30\u5316\u94be<\/p>\n
\u5e38\u89c1\u7684\u91d1\u5c5e\u6c2e\u6742\u73af\u5361\u5bbe\u50ac\u5316\u5242<\/p>\n
<\/p>\n
\u5e38\u89c1\u91d1\u50ac\u5316\u5242<\/p>\n
\u5e38\u89c1\u50ac\u5316\u5242—-Cp*Co(CO)I2<\/p>\n
\u5e38\u89c1\u5149\u50ac\u5316\u5242<\/p>\n
\u5e38\u89c1\u7684\u94d1\u50ac\u5316\u53cd\u5e94<\/p>\n
\u5e38\u89c1\u7684\u954d\u50ac\u5316\u53cd\u5e94<\/p>\n
\u5e38\u7528\u50ac\u5316\u5242—-Ni(COD)2 \u7684\u5e94\u7528<\/p>\n
\u5e38\u7528\u8bd5\u5242—-\u6c2f\u5316\u954d<\/p>\n
\u9f50\u683c\u52d2-\u7eb3\u5854\u50ac\u5316\u5242<\/p>\n
\u5e38\u89c1\u94af\u50ac\u5316\u5242\u7684\u5236\u5907<\/p>\n
\u6709\u673a\u5408\u6210\u4e2d\u5e38\u89c1\u7684\u81a6\u914d\u4f53<\/p>\n
Alper\u7fb0\u57fa\u5316\u53cd\u5e94<\/p>\n
<\/p>\n
\u90bb\u4f4d\u542b\u6709\u8102\u80aa\u80fa\u7684\u5364\u4ee3\u82b3\u70c3\uff0c\u70ef\u57fa\u80fa\uff0c\u70ef\u57fa\u6c2e\u6742\u73af\u4e19\u80fa\u7b49\u7b49\u548c\u4e00\u6c27\u5316\u78b3\u5728Pd\uff0cRu\u6216Rh\u7b49\u50ac\u5316\u5242\u50ac\u5316\u4e0b\uff0c\u8fdb\u884c\u63d2\u7fb0\u5173\u73af\u5236\u5907\u73af\u9170\u80fa\u7684\u53cd\u5e94\u3002<\/p>\n
Liebeskind\u5076\u8054\u53cd\u5e94<\/p>\n
2000\u5e74Libeskind\u548cSrogl\u63d0\u51fa\u4e86\u4e00\u79cd\u5728\u4e2d\u6027\u6761\u4ef6\u4e0b\uff0c\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u786b\u916f\u548c\u787c\u9178\u8fdb\u884c\u5076\u8054\u5f97\u5230\u916e\u7684\u65b0\u65b9\u6cd5\u3002\u5728\u5316\u5b66\u8ba1\u91cf\u7684\u567b\u5429-2-\u7fa7\u9178\u4e9a\u94dc\uff08CuTC\uff09\u548c\u50ac\u5316\u91cf\u7684\u94af\u50ac\u5316\u4e0b\uff0c\u786b\u4ee3\u9178\u916f\u548c\u82b3\u57fa\u787c\u9178\u6216\u70f7\u57fa\u787c\u8fdb\u884c\u5076\u8054\u5f97\u5230\u916e\u7684\u53cd\u5e94\u88ab\u79f0\u4e3aLibeskind\u5076\u8054\u53cd\u5e94\u3002\u6b64\u53cd\u5e94\u662f\u975e\u5e38\u91cd\u8981\u7684\u628a\u7fa7\u9178\u53ca\u5176\u884d\u751f\u7269\u8f6c\u5316\u4e3a\u916e\u7684\u65b9\u6cd5\uff0c\u6b64\u53cd\u5e94\u4e2d\u787c\u9178\u6216\u70f7\u57fa\u787c\u4e3a\u975e\u78b1\u6027\u4eb2\u6838\u8bd5\u5242\uff0c\u56e0\u6b64\u53cd\u5e94\u6761\u4ef6\u6bd4Fuyama\u5076\u8054\u66f4\u6e29\u548c\u3002<\/p>\n
Trost\u73af\u620a\u70f7\u5316\u53cd\u5e94<\/p>\n
\u94af\u50ac\u5316\u4e0b\uff0c\u4e59\u9170\u6c27\u7532\u57fa\u70ef\u4e19\u57fa\u7845\u70f7\u548c\u7f3a\u7535\u5b50\u70ef\u70c3\u901a\u8fc7[2+3]\u73af\u52a0\u6210\u5236\u5907\u73af\u620a\u70f7\u7684\u53cd\u5e94\u3002<\/p>\n
\u94af\u50ac\u5316\u7684C-O\u952e\u5f62\u6210\u53cd\u5e94<\/p>\n
\u94af\u50ac\u5316\u7684C-O\u952e\u5f62\u6210\u53cd\u5e94\u6761\u4ef6\u548cC-N\u5f62\u6210\u53cd\u5e94\uff08Buchwald\u53cd\u5e94\uff09\u7c7b\u4f3c\u3002\u5728Pd\/\u5bcc\u7535\u5b50\u81a6\u914d\u4f53\u50ac\u5316\u4e0b\uff0c\u915a\uff0c\u4f2f\u9187\u548c\u4ef2\u9187\u90fd\u53ef\u4ee5\u548c\u82b3\u5364\u6216\u70ef\u57fa\u5364\u4ee3\u7269\u53cd\u5e94\u3002\u5206\u5b50\u5185\u548c\u5206\u5b50\u95f4\u90fd\u53ef\u4ee5\u8fdb\u884c\u3002\u7279\u6b8a\u60c5\u51b5\u4e0b\u53d4\u9187\u4e5f\u53ef\u4ee5\u8fdb\u884c\u6b64\u53cd\u5e94\u3002<\/p>\n
Stoltz \u03b1-\u70ef\u4e19\u57fa\u916e\u4e0d\u5bf9\u79f0\u5408\u6210\u53cd\u5e94<\/p>\n
\u624b\u6027\u6076\u5511\u5549\u81a6\u914d\u4f53PHOX\uff084\uff09\u914d\u4f4d\u7684\u94af\u50ac\u5316\u5242\u50ac\u5316\u73af\u72b6\u03b2-\u916e\u70ef\u4e19\u916f\u916f\uff0c\u901a\u8fc7\u03c0-\u70ef\u4e19\u57fa\u4e2d\u95f4\u4f53\u5f97\u5230\u5355\u4e00\u6784\u578b\u7684\u03b1-\u70ef\u4e19\u57fa\u73af\u916e\u7684\u53cd\u5e94\u3002<\/p>\n
\u5432\u54da\u5408\u6210\u7c7b<\/p>\n
Hegedus\u5432\u54da\u5408\u6210\u53cd\u5e94<\/p>\n
\u5316\u5b66\u5f53\u91cf\u7684Pd(II)\u50ac\u5316\u5242\u6c27\u5316\u73af\u5316\u94fe\u70ef\u57fa\u80fa\u5f97\u5230\u5432\u54da\u7684\u53cd\u5e94\u3002\u53cd\u5e94\u673a\u7406\u548cWacker\u6c27\u5316\u7c7b\u4f3c\u3002<\/p>\n
<\/p>\n
Larock\u5432\u54da\u5408\u6210\u53cd\u5e94<\/p>\n
1991\u5e74\uff0cR.C. Larock\u9996\u5148\u62a5\u9053\u4e86\u5728\u94af\u50ac\u5316\u4e0b\u75312-\u7898\u80fa\u548c\u53d6\u4ee3\u7094\u70c3\u5173\u73af\u5408\u6210\u5432\u54da\u7684\u53cd\u5e94\u3002\u5728\u4ee5\u540e\u7684\u51e0\u5e74\u4e2dLarock\u7684\u56e2\u961f\u53c8\u5bf9\u6b64\u53cd\u5e94\u7684\u5e94\u7528\u8303\u56f4\u8fdb\u884c\u4e86\u8fdb\u4e00\u6b65\u7684\u6269\u5c55\u3002\u5728\u94af\u50ac\u5316\u4e0b\uff0c\u90bb\u7898\u80fa\u548c\u4e8c\u53d6\u4ee3\u7094\u70c3\u8fdb\u884c\u6742\u73af\u5316\u5408\u62102,3-\u4e8c\u53d6\u4ee3\u5432\u54da\u7684\u53cd\u5e94\u88ab\u79f0\u4e3aLarock\u5432\u54da\u5408\u6210\u53cd\u5e94\u3002<\/p>\n
\u901a\u8fc7\u5206\u5b50\u5185\u7684Heck\u53cd\u5e94\u5408\u6210\u5432\u54da<\/p>\n
DABCO\u4f5c\u78b1\uff0c\u5728DMF\u4e2d\u53cd\u5e94\u6548\u679c\u8f83\u597d\u3002<\/p>\n
Mori-Ban\u5432\u54da\u5408\u6210\u53cd\u5e94<\/p>\n
\u542b\u6709\u70ef\u4e19\u80fa\u7ed3\u6784\u7684\u90bb\u5364\u4ee3\u80fa\u53d1\u751f\u5206\u5b50\u7684Heck\u53cd\u5e94\u5236\u5907\u5432\u54da\u7684\u53cd\u5e94\u3002<\/p>\n
Narasaka-Heck\u73af\u5316\u53cd\u5e94<\/p>\n
Murahashi\u5076\u8054\u53cd\u5e94<\/p>\n","protected":false},"excerpt":{"rendered":"
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